Oystein
Penultimate Amazing
- Joined
- Dec 9, 2009
- Messages
- 18,900
It took a bit of research to realize that you most probably meant chestnuts ("marrons" or "chàtaignes" in French, castañas in Spanish).
Yes. "Kastanien" or "Maronen" in German.
It took a bit of research to realize that you most probably meant chestnuts ("marrons" or "chàtaignes" in French, castañas in Spanish).
...
No need to wait for results, Ziggi. ...
...Harrit et. al. have claimed they found Fe:O ratios of up to 4:1, but only for the spheroid appearing in Fig. 21. If this claim can be validated, that would indicate reduction of iron...
But, they have NOT provided any details as to their "conventional quantitative analysis" which they claim provided the 4:1 Fe:O ratio measurement....
Nor have they performed similar "conventional quantitative analyses" for many other samples exhibiting obvious dominance of oxygen over iron in the XEDS, such as Fig. 24 (commercial thermiteTM, oxygen peak towers over iron peak), Fig. 26 (another DSC spheroid, oxygen peak towers over iron peak), and Fig. 27 (WTC dust spheroid, oxygen peak towers over iron peak). ....
Meanwhile, truthers have criticized my experiments showing production of iron-rich spheroids via means besides ThermiteTM, mainly on the basis of these spheroids having oxygen peaks in XEDS, and thus possible iron oxide content (as can also be argued for spheroids in Harrit's Fig. 24 (commercial thermiteTM), Fig. 26 (another DSC spheroid), and Fig. 27 (WTC dust spheroid).....
....No dirty burn barrels, no uncontrolled environments. I expect to get microspheres from all of these methods. In addition to XEDS examinations of spheroid composition, I am also looking at "conventional quantitative analysis routines" to answer the question:
Which of these iron-rich spheroids are composed of elemental iron? Which have significant amount of iron oxides?
Now that school is out for the semester, I'm starting to get serious.
No need to wait for results, Ziggi. Why don't you just debunk my experiment now, before it even happens?
Now, that was not that difficult was it? The data shows that upon ignition the red material goes through a reaction that reduces the iron-oxide, as is expected with a thermite reaction. The reaction that melted the iron-oxide, was in other words not a conventional oxidation reaction, aka normal carbon fueled burning/oxidation.
Now I understand, they figure everyone will assume they know what they're talking about because the intended audience does.That´s because the expected audience for chemistry journals is assumed to understand the basics, as the word "conventional" in the phrase "conventional quantitative analysis" indicates.
Now, that was not that difficult was it? The data shows that upon ignition the red material goes through a reaction that reduces the iron-oxide, as is expected with a thermite reaction. The reaction that melted the iron-oxide, was in other words not a conventional oxidation reaction, aka normal carbon fueled burning/oxidation.
That´s because the expected audience for chemistry journals is assumed to understand the basics, as the word "conventional" in the phrase "conventional quantitative analysis" indicates.
The spectra in figures with elements besides iron show large oxygen peaks because only the iron is reduced while the aluminum, and carbon and silicon additives are oxidized when the reaction occurs in air.
You have been criticized for posting experiments where you gave the false impression that spheres were formed even though none were formed, and for not understanding the topic at hand. When you burned/oxidized your steel wool you did not understand that you were demonstrating an oxidation reaction that began with pure metal and ended up with an oxide, which is the exact opposite to the reaction shown by Harrit et al., and you did not understand that you only blew up parts of the steel wire like a balloon and formed objects that look similar to previously melted spheres but are not the real thing.
If you repeat your steel wool and barrel burn experiments and cheat the 700C temperature limit of Harrit´s DSC and the 1000C limit of an open air fire with a torch(oxy-acetylene perhaps) that is hot enough to actually achieve the melting-point temperatures of the iron-based materials in the wire, the beams, the paint etc, you could melt those materials and perhaps even form spheres. You could do the same thing with a DSC set to maybe 1800C or some sort of a blast furnace as used by power-plants.
This way you could end up forming spheres but since you would be burning/oxidizing the metal you would end up with an oxide as is the case with the fly-ash spheres from power plants. This is the opposite process to reduction. This is not about comparing the oxygen levels of spheres formed via different processes; This is about noting the type of reaction which means oxidation vs reduction.
To challenge Harrit you would have to melt and reduce 100nm iron-oxide in a DSC or oven or some other sort of a controlled air environment limited to 700C. Find a scientist willing to put his name along with yours and publish in a scientific journal. Don´t expect Dr. Harrit to respond to YouTube videos.
What does the adjective "conventional" actually mean, very specifically, in this context?That´s because the expected audience for chemistry journals is assumed to understand the basics, as the word "conventional" in the phrase "conventional quantitative analysis" indicates.
Ziggi experiments? Which?Has anyone ever seen any of ziggi's experiments?
Ziggi, did you ever do any such tests? Where are the results?JM Talboo said:One thing that you're [Ziggi] gonna be doing is, Mark has sent me one of these samples of World Trade Center primer paint, and in the original "Active thermitic material" paper, Steven Jones has a video where he shows, the take one of these paint chips and take an oxy-acetylene torch to it, and touch it to the chip and get it close, and it flashes again upon ignition, a really brilliant flash. They say when they did this with ... just the World Trade Center primer paint, that it just reduced to fragile ashes, but the thing is, we don't have a video to show that. So that's what we're hoping you [Ziggi] can get for us. I'm gonna send you [Ziggi] this chip, and hopefully you [Ziggi] can show that it does just reduce to fragile ashes, and then I'm gonna send along some other just random paint samples, too, to see what happens
I am not your "pal." Please do not refer to me as your "pal", "buddy", or etc.
Harrit et. al. have claimed they found Fe:O ratios of up to 4:1, but only for the spheroid appearing in Fig. 21. If this claim can be validated, that would indicate reduction of iron.
But, they have NOT provided any details as to their "conventional quantitative analysis" which they claim provided the 4:1 Fe:O ratio measurement. Nor have they performed similar "conventional quantitative analyses" for many other samples exhibiting obvious dominance of oxygen over iron in the XEDS, such as Fig. 24 (commercial thermiteTM, oxygen peak towers over iron peak), Fig. 26 (another DSC spheroid, oxygen peak towers over iron peak), and Fig. 27 (WTC dust spheroid, oxygen peak towers over iron peak).
You have ignored these key points before.
Yes, I understand Harrit et. al's claim, as I have explained oh-so-many-times.
If you'll stop with the lecturing and pretending to be smart, I will re-iterate this for you once again.
Harrit's experiment is in shambles. It has not convinced the scientific community that nanothermites were used to demolish the Twin Towers. It was marred by missed measurements and confused "analyses." Harrit's experiment was such a flop, truthers have raised $5000 to revisit the analyses with new experiments and data, but I think that effort itself has degenerated into partisan squabbles: it has failed. Not surprising, considering the ringleaders for that circus.
Meanwhile, truthers have criticized my experiments showing production of iron-rich spheroids via means besides ThermiteTM, mainly on the basis of these spheroids having oxygen peaks in XEDS, and thus possible iron oxide content (as can also be argued for spheroids in Harrit's Fig. 24 (commercial thermiteTM), Fig. 26 (another DSC spheroid), and Fig. 27 (WTC dust spheroid).
So, I am planning on carrying out a new, improved experiment. I plan to investigate a number of methods for producing iron-rich microspheroids, to include cutting steel, grinding steel, using flint, oxidation/reduction reactions, heating paint chips from steel beams until they "explode", commercial ThermiteTM, as well as using aluminum-foil coated cannonballs to produce thermitic spheroids (with the activation energy required for the thermitic reaction supplied by the kinetic energy of the colliding cannonballs).
No dirty burn barrels, no uncontrolled environments. I expect to get microspheres from all of these methods. In addition to XEDS examinations of spheroid composition, I am also looking at "conventional quantitative analysis routines" to answer the question:
Which of these iron-rich spheroids are composed of elemental iron? Which have significant amount of iron oxides?
Now that school is out for the semester, I'm starting to get serious.
No need to wait for results, Ziggi. Why don't you just debunk my experiment now, before it even happens?
What a fantastic experiment, using an oxy-acetylene torch on paint chips
I wonder what could possibly happen ?
I'm no chemist but I'll take a stab at it and say, reduce to ash? I say this because I suspect that there are a lot of common materials that reduce to ash when subjected to temps in the vicinity of 1000 degree C in normal atmospheric conditions.
You mean conditions like this might have been true!!!....burn paper inside a red painted filing cabinet, and check for microspheres, you will find thousands.
The smoldering paper creates the perfect reduction environment for Iron oxide reduction.
All the lab work and chemical equations aside, the fires at the WTC complex during the month of September 2001 contained a myriad of materials and a spectrum of oxygen availability and temperatures. Reduced iron microspheres could have been produced without thermite.
So yes, yes, yes, Harrit should have done comparisons if he was going to claim they MUST indicate thermite.
I'm no chemist but I'll take a stab at it and say, reduce to ash? I say this because I suspect that there are a lot of common materials that reduce to ash when subjected to temps in the vicinity of 1000 degree C in normal atmospheric conditions.
Hmm and what if that paint adhered to, say, a gray layer of steel mill?
Hmm and what if that paint adhered to, say, a gray layer of steel mill?
Ziggi experiments? Which?
Oh wait:
http://nanothermite911.blogspot.de/2014/02/911-free-fall-2614-guest-host-john.html
Ziggi, did you ever do any such tests? Where are the results?
Reported it, ok.
How was this determined?
One point is even more important: What kind of ratio was determined? Mass ratio? Atomic ratio? This point was not referenced in the whole paper.
Harrit et al said:after accounting for oxygen fractions to trace elements,
it is found that the Fe:O ratio for the spectrum in Fig.
(18) is approximately 2:3. This indicates that the iron is oxidized
and apparently in oxidation state III, indicating that Fe2O3, or
perhaps an iron (III) oxo-bridged polymer, is present.
Now, that was not that difficult was it? The data shows that upon ignition the red material goes through a reaction that reduces the iron-oxide, as is expected with a thermite reaction. The reaction that melted the iron-oxide, was in other words not a conventional oxidation reaction, aka normal carbon fueled burning/oxidation.
That´s because the expected audience for chemistry journals is assumed to understand the basics, as the word "conventional" in the phrase "conventional quantitative analysis" indicates.
The spectra in figures with elements besides iron show large oxygen peaks because only the iron is reduced while the aluminum, and carbon and silicon additives are oxidized when the reaction occurs in air.
You have been criticized for posting experiments where you gave the false impression that spheres were formed even though none were formed, and for not understanding the topic at hand. When you burned/oxidized your steel wool you did not understand that you were demonstrating an oxidation reaction that began with pure metal and ended up with an oxide, which is the exact opposite to the reaction shown by Harrit et al., and you did not understand that you only blew up parts of the steel wire like a balloon and formed objects that look similar to previously melted spheres but are not the real thing.
If you repeat your steel wool and barrel burn experiments and cheat the 700C temperature limit of Harrit´s DSC and the 1000C limit of an open air fire with a torch(oxy-acetylene perhaps) that is hot enough to actually achieve the melting-point temperatures of the iron-based materials in the wire, the beams, the paint etc, you could melt those materials and perhaps even form spheres. You could do the same thing with a DSC set to maybe 1800C or some sort of a blast furnace as used by power-plants.
This way you could end up forming spheres but since you would be burning/oxidizing the metal you would end up with an oxide as is the case with the fly-ash spheres from power plants. This is the opposite process to reduction. This is not about comparing the oxygen levels of spheres formed via different processes; This is about noting the type of reaction which means oxidation vs reduction.
To challenge Harrit you would have to melt and reduce 100nm iron-oxide in a DSC or oven or some other sort of a controlled air environment limited to 700C. Find a scientist willing to put his name along with yours and publish in a scientific journal. Don´t expect Dr. Harrit to respond to YouTube videos.
...You have yet to deal with the obvious problem this concession on your part creates for 9/11 Truth: the Twin Towers were not a sterile lab environment, either, and truther reports of "iron spheroids can only be formed by Thermite" fall apart when one considers the many ways that these spheroids can be formed (grinding, cutting, burning, etc.).
If I can get a materials scientist to help out/co-publish, that would be splendid.
But don't knock YouTube, my burn barrel video has over 2000 views, while the Harrit/Bentham paper has a mere 48 Google Scholar citations, and most of those are from political or psychological journals.
In fact, I could only find one paper referring to Harrit/Bentham from an actual materials scientist. Some guy named Millette.
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Originally Posted by chrismohr View Post
I just talked with Jim Millette. In the next couple weeks he plans to write up a short followup on the progress of his research, with some of his thin section work expanded upon and the process of elimination he is going through as he tries to identify the specific source of the red-gray chips.
Then, in the end of April, he will give another progress report, this time on his research into the iron-rich microspheres.
He also said that this project is so big, it may end up being several peer-reviewed papers, not just one. And no, there is no set date for publication. A big project will take time.
... the remnants of an energetic red material were found in the dust in the form of miniscule red/gray chips, ...
The only reaction that forms iron spheres is the oxidation-reduction thermite reaction.
You have a citation from a reputable source in metallurgy or chemistry to back this bold statement up?The only reaction that forms iron spheres is the oxidation-reduction thermite reaction.
Major? How is that determined?The WTC Towers were indeed not sterile, the remnants of an energetic red material were found in the dust in the form of miniscule red/gray chips, and we already know this red material is one major source for the iron rich spheres found in the WTC dust, if not the only one.
No, we might conclude that iron spheres are created by an aluminum reduction of iron oxide in the chips. Are all aluminum reduction of iron oxide reactions referred to as thermite reactions?Your obvious problem is that the data by Harrit et al show that this material forms melted iron spheres via an oxidation-reduction reaction that uses aluminum to reduce iron-oxide, otherwise known as a thermite reaction. We therefore already know that a principal source for those WTC iron spheres was a thermitic material.
Whew, then Youtube can also be ignored by NIST. That takes a load off.YouTube won´t do if you want Dr. Harrit to notice your work
Well then that makes it all better doesn't it.Millette was also researching the iron sphere issue and he also had big plans to publish..but then he went silent and was never heard from again:
Thanks for putting that in writing!
Does anyone have any idea what this is all about
Are we talking thermite ?
http://survivaltopics.com/flint-and-steel-what-causes-the-sparks/
And your point is?? Dr. Harrit put that in writing 5 years ago in his response to Rancourt, but you did not understand it then and it seems you still have not understood it despite all the discussion here now. Do you have any sort of a real response to my last post or is this all you got?
Hmm, why would I thank you for saying "The only reaction that forms iron spheres is the oxidation-reduction thermite reaction." ?
If you would stop your lecturing and trying to look smart, you might even figure it out!
Well sparks of that sort are oxidizing iron, not reducing iron oxide. However, the spheres in the picture are paramagnetic, according to the article, so its not all Fe2O3.
Since a spark is the chipping off and burning of a small chunk of iron, its quite possible that the surface oxidizes while the interior, not coming into contact with air, stays purely iron. A larger, shall we call it, millisphere, could end up as a microsphere simply by evaporating the oxidized outer layer.
No? Yes?
None of it is Fe2O3, it's FeO- Fe3O4.
Hmm, why would I thank you for saying "The only reaction that forms iron spheres is the oxidation-reduction thermite reaction." ?
If you would stop your lecturing and trying to look smart, you might even figure it out!
Originally Posted by Ziggi View Post
And your point is?? Dr. Harrit put that in writing 5 years ago in his response to Rancourt, but you did not understand it then and it seems you still have not understood it despite all the discussion here now. Do you have any sort of a real response to my last post or is this all you got?
Originally Posted by DaveThomasNMSR View Post
You've got something there, Spanx!
the particle of iron spontaneously becomes so hot that it glows as it oxidizes
This way you could end up forming spheres but since you would be burning/oxidizing the metal you would end up with an oxide as is the case with the fly-ash spheres from power plants. This is the opposite process to reduction. This is not about comparing the oxygen levels of spheres formed via different processes; This is about noting the type of reaction which means oxidation vs reduction.
The only reaction that forms iron spheres is the oxidation-reduction thermite reaction. ... we already know this red material is one major source for the iron rich spheres found in the WTC dust, if not the only one. ...
I am not forgetting the many questions you are already dodging, but I have two more:
Did the iron rich spheres found in the WTC dust form from the red layer of the red/gray chips or from the gray layer?
Did they form by a thermite reaction with aluminium, and aluminium only?
Dave Thomas and Oystein are way ahead on points on this one.Dave, are you too embarrassed to reveal the answer yourself? There is nothing for me to figure out - unless you come up with a better explanation it just looks like you posted that comment because you still have not understood the topic at hand:
Further proof that you have still not understood the discussion is your comment to Spanx:
The article he referred to is of course about iron being burned/oxidized, not reduced:
But I have been struggling - unsuccessfully obviously - to make you understand the difference between that and the process shown by Harrit et al:
Where?![]()
Post #1595 oh unobservant one.