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Subsonic 'explosions' as cause of pulverization

metamars

Graduate Poster
Joined
Apr 4, 2007
Messages
1,207
The thread is split off from

Jones New Paper: Microspheres and Temperatures

Basically, I had suggested a low velocity blast of less than 100 mph, from a tempered thermobaric, as source of the pulverisation. Some people on that thread keep missing the point that I am not positing this as a source of the columns' destruction, but rather pulverization of most of the other stuff. Besides the visuals of the buildings as they were coming down, recall reports of not finding a piece of a phone bigger than the touchpad, or the scarcity of photos that show even a squashed computer screen or shard of glass.

There was some back and forth on this, which you can read in the other thread. Mr. Mackey's last post to me on the subject is:

:eye-poppi Hokey smokes!!

You're going to get Stundied for that one. I'm not going to do it, and I don't participate in teh Stundies, I'm just warning you.

Either you're playing dumb to gain some leverage off my sense of charity (not a bad strategy) or you're even more confused than I could have imagined. But I'll try to help. We have to go back to Square One for this.

There is, by definition, no possible explosive of any kind with such a low blast front speed. Remember what we're talking about, here. The "blast front" you are describing is a pressure wave. In the case of a high explosive, like TNT or RDX, the "blast front" is a shock wave, and is therefore supersonic. The speed depends on a lot of things but will exceed 340 m/s, or 770 MPH to use your choice of units. A low explosive, like black powder, does not generate a shock wave, instead generating a possibly large in amplitude, but not sharp, pressure wave. This wave moves at the speed of sound, 770 MPH.

The sound speed is the minimum speed of the "blast front." There is no explosive, not of any kind, that will go a mere 100 MPH.

To get such a slow speed, you're not talking about explosives any more, nor a "blast front." That kind of speed, being at Mach numbers of < 0.15, is definitely in the regime known as "incompressible flow." Since we're not setting off this strange device in a sealed chamber, the static air pressure remains constant. The only forces are kinetic, i.e. what "pressure" you feel is strictly due to the air's velocity. Your device will simulate the effect of a 100 MPH gust of wind.

Because the force is purely kinetic, we can calculate the actual felt pressure directly -- it only depends on speed in this case. Using the Bernoulli equation, the felt pressure is equal to ρ v2 / 2, where ρ is the density of air, and v is the speed of the air at infinity.

In your case, the speed is your mandated 100 MPH (about 45 m/s), and air density is about 1.2 kg / m3. The felt pressure then works out to about 1200 kg m2 / (s2 m3), or 1.2 kPa. In archaic units, this is 0.17 PSI.

That's it. Not even enough to break windows. Abandon this hypothesis now.

The only way you can reconcile such a slow airflow speed with structural damage is if your mystery device is in mechanical contact with the structure -- rather than transmit a "blast wave," it just pushes on the columns. That, of course, can be done as slow as you wish.

So rather than focus on hyperbaric explosives, you should instead start looking into hypotheses involving, for instance, expanding foam, or (dare I say) collapse of the upper structure.

If you need still further help, as I imagine you do, please start another thread. This is long overdue.

My answer, on this brand spanking new thread, is:

Well, .17 psi overpressure isn't going to pulverize much of anything. It's not entirely clear to me, though, whether the .17 psi represents the effect of a single plane wave, or a continuous train of waves. Do you know which it is? And if the latter, how dense can these wave fronts be, and will the effects be additive, in some sense?

Thanks to your post, I spent time - too much, it seems, yet still not enough - googling around for info on deflagrations, thermite, solid propellants, etc. Basically, I am trying to get a sense of whether or not 'mild' controlled explosions can 'shoot' ferrous by-products subsonically at hundreds of mph, yet still not create a purely gaseous pressure wave that exceeds 170 mph. (170 mph limit for a WTC window is guesstimated from http://www.litchfield-group.co.uk/sheerframe/news/walling-index.asp?story=20060413 ) I assume this would not be from a thermobaric, since dispersing the reactants first would make for more of a mismatch between a blast wave containing ferrous molecules ( about 3,000x as dense as air molecules ), and a concomittant gaseous pressure wave. We either want an air pressure wave which never exceeds 170 mph (or whatever the correct limit is for the WTC windows), or else one which does, but the trailing particle front is close enough, and moving fast enough, so that we can't distinguish it as a separate event. I think this argues for point sources, not dispersed ones. (Hence, again, we're not talking about thermobarics.)

Now, consider:
(caveat emptor-I haven't done much double checking of my calculations. However, the Giants are going to beat the Patriots, and the game is starting in only 20 minutes. First things first!)


A .22 Long rifle takes a 40 grain bullet, with muzzle velocity 1255 ft/s, or 2.6 gram and 382 m/s, giving a momentum of roughly .99 kg-m/s

So, 10,000 bullets would give us a momentum of 9900 kg-m/s

a mole of Fe203 + 2 moles of Al will weigh 210 grams, and have a heat energy of 853 kJ

If .5% of this can be utilized to impart kinetic energy to the reactants (via rapid heating of gases), then we can compute the speed from

.005 * 853,000 = .5 * .21 * v^^2

v = sqrt ( 853,000 )


201 m/s = 449 mph < 770 mph = speed of sound in air


This would represent a momentum of .21 kg * 201 m/s = 42.21 kg-m/s.


To get the equivalent momentum of 10K bullets, you would need (9900 / 42.21) * .21 kg, or about 50 kg of 'exploding thermite'.


This calculation is suggestive, at best. I've not made any attempt to rigorously determine what gas speeds would be associated with a thermite explosion with a .5% conversion efficiency to KE. I also have no idea how quickly the thermite would heat up. Presumably, you want it to heat up quickly, so that it can pulverize via burning through, not just kinetic energy. Perhaps we need a sophisticated nano-thermite, not regular thermite.

Recall that the red-gray chips have a red side (that Professor Jones believes is thermite) of thickness 40 microns. This is about equal to the radius the "preferred" sized aluminum particle in a solid fueled rocket engine, if I read the following correctly: http://dspace.dsto.defence.gov.au/dspace/bitstream/1947/3835/1/DSTO-GD-0344 PR.pdf

Generally the aluminium content will vary between 5 and 25 wt% with 15 wt% being common. The particle size of the aluminium affects the plateau burning behaviour. A large particle size from 80 - 120 micrometer is preferred.

Counter-arguments that readily come to mind are: 1) I would expect liquid metal droplets to get deformed as they slam into any solids. Thus, I would expect most of them not to be spherical. 2) I would think that there would be ubiquitous mottling. Just like I don't believe that a column punching through a floor element will cause it to disintegrate far from it's impact area, I also wouldn't expect a tiny piece of metal traveling at, say, 250 mph to destroy a structure many times it's surface area. Of course, if you had millions of them, that might be another story.

Hmmm. I was going to sign off, but this is too tempting.

Well, I recently came across the density of rust. It is 4 g / cm3. If we pretend that one of Professor Jones' chip (red side) has a similar density, then know that there would be ~ (10^^-6 m^^3/ .004 kg) / {(.001 m)^^2 * 4x10^^-5 m} chips, or about 6 million.

At 44,000 sq ft per floor in a WTC tower, this works out to about 136 thermite chip-projectiles per square foot.
 
Basically, I had suggested a low velocity blast of less than 100 mph, from a tempered thermobaric, as source of the pulverisation.


Um ... large passenger jets hit the buildings.
 
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Basically, I had suggested a low velocity blast of less than 100 mph, from a tempered thermobaric, as source of the pulverisation.
This just in: concrete pulverized by moderately strong wind from impossible weapon, not by thousands of tons of collapsing building. Stay tuned for more at 11..............

I assume this would not be from a thermobaric,
Hey, that's progress! Know why? Because a thermobaric weapon is an EXPLOSIVE.

I think this argues for point sources, not dispersed ones.
I got yer "point source" right here:
WTCBeforeWFC-full.jpg



Now consider: [babbling deleted]
Now consider this, metamars: the quarter-mile high buildings collapsed and crushed their contents. I know reality sucks, but you can either live with it or keep drifting farther and farther from the shore.

Which will it be?
 
At 44,000 sq ft per floor in a WTC tower, this works out to about 136 thermite chip-projectiles per square foot.
Paint chips, you mean.

Welcome to Christopheraville.
 
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Sweet merciful crap, this is still going on.

But I thank you for starting a new thread.

The 0.17 PSI estimate I made is neither a "wave" nor a "Train of waves." That thinking is ludicrous. The minimum speed of a wave in atmosphere is the speed of sound. I can't believe I have to tell you this again, but there we are. No matter how faint, how slight, approx. 770 MPH is the minimum speed for any pressure disturbance to propagate in the atmosphere near sea level. The output of any explosive is a pressure wave. That means, to a fixed observer, the pressure measured as a function of time rapidly increases, then decays as the wave passes. There is no "train of waves," though there can be multiple reflecting waves. There is no "interference," these waves simply add or subtract. You cannot have significant additive effects unless you have rigid reflectors, i.e. something strong enough to stand up to your explosive and direct the blast elsewhere. Shaped charges do this, of course. But not at low speed. Supersonic only.

If you want slower, you're not sending a pressure wave. You're moving the air itself. Like turning on a fan, for instance. You'll hear the fan turn on much sooner than the breeze gets to you. That breeze, as shown before, is in the sub-PSI range and won't "explode" anything.

Yes, you could devise something that lobbed projectiles at 100 MPH, for instance, and pushed the columns around that way. This device is not an "Explosive." This device is a "gun."

You bring up the example of a .22LR round. Most .22LR's are supersonic, but there are plenty of subsonic guns, e.g. .45ACP, muzzle-loaders, or large mortars. You've forgotten, however, that the .22LR round also makes noise! Even a subsonic gun has muzzle blast, and that does indeed travel at the speed of sound (or faster).

A whomping great low-velocity cannon like you would be forced to propose, big enough to damage the WTC structure, would issue a thunderous report, and this would probably even be visible in the smoke, even if no muzzle flash was issued.

So now you need a silencer. Perhaps, instead of the perfectly reasonable gravity-driven collapse, there were enormous, whomping cannons just below the fire and impact floors, lobbing multiton projectiles against the structure, all fitted with silencers the size of garbage trucks. Sure, it's physically possible.

It's also completely nuts.
 
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Besides the visuals of the buildings as they were coming down, recall reports of not finding a piece of a phone bigger than the touchpad, or the scarcity of photos that show even a squashed computer screen or shard of glass.

If the "Truth Movement" people ever learn to recognize metaphor and simile when used, the movement will self-dustify and disappear in a pyroclastic cloud like a freight train.

The "phone pad" quote is from the Naudet film. It is said by a fireman in an after-the fact interview while footage of the building debris is shown. It wasn't literally accurate. Who knows why he said it.
http://video.google.com/videoplay?docid=6371069744838112957&q=Naudet
 
The "phone pad" quote is from the Naudet film. It is said by a fireman in an after-the fact interview while footage of the building debris is shown. It wasn't literally accurate. Who knows why he said it.
http://video.google.com/videoplay?docid=6371069744838112957&q=Naudet

The fact that that was the largest piece he found may have something to do with where on the pile he was searching. At the perimeter, I would expect to find nothing larger. Under the steel beams in the middle of the footprint, I should expect more and larger objects, such as the meteor.

Fire fighters would probably be assigned specific sectors by unit, just like a military operation. It helps maintain accountability in a hazardous environment.
 
The "phone pad" quote is from the Naudet film. It is said by a fireman in an after-the fact interview while footage of the building debris is shown. It wasn't literally accurate. Who knows why he said it.
http://video.google.com/videoplay?docid=6371069744838112957&q=Naudet


Aside from the fact that the comment was from immediately after the day (well before most of the debris was sorted), about 40,000 people worked on the debris pile. I'd be quite surprised if anyone handled every single piece of debris.
 
I talked to my solid state physics prof after class tonight about this. I asked about whether it would be possible to have a subsonic, non-explosive 'explosion', which could destroy things by virtue of it's momentum, pointing out that a pressure wave of 100 mph will only exert an overpressure of .17 psi. I mentioned that, e.g., the model rockets I used to shoot off made a 'whooshing' sound, not a bang, so I am thinking of something like a solid rocket fuel, but with mass deriving from metallic components. I mentioned aluminotherics could explode, and that metallic constituents of the chemical reactants would be far more massive than air molecules. (I didn't explicitly mention thermite, or ferrous constituents.)

He told me to check out magneto waves, Magnetic Hydro-Dynamics, and Alfven (waves?). He said he thought that keeping subsonic should be doable if you control the burn rate. He wasn't too sure about who to best ask regarding the destructiveness, but he seemed to agree that a chemical engineer would be a good person to ask.

He said that the magneto waves in dielectrics are sound waves, but of a sort that travel much slower than regular sound waves. I asked him what sort of dielectrics one could use, and he said "rocket fuel".

Any miscommunication between my professor and myself is probably my fault!

-----------------------------------------

On a related note:
From http://pdf.aiaa.org/preview/CDReadyMASM03_582/PV2003_241.pdf

In another study, Aumann et al. (1995) examined the oxidation behavior of aluminum nanopowders. They suggest that Al powder mixtures with average particle sizes of 20-50 nm can react 1000 times faster than conventional powdered thermites..
 
Good luck with your hypothesis that the Twin Towers were pushed around by little rocket chips. You'll find that this is a viable source of Alfven waves:

879047a92c6745729.jpg

Be sure to let us know when you get back to Earth, and remember to change your foil weekly.
 
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I talked to my solid state physics prof after class tonight about this. I asked about whether it would be possible to have a subsonic, non-explosive 'explosion', which could destroy things by virtue of it's momentum, pointing out that a pressure wave of 100 mph will only exert an overpressure of .17 psi. I mentioned that, e.g., the model rockets I used to shoot off made a 'whooshing' sound, not a bang, so I am thinking of something like a solid rocket fuel, but with mass deriving from metallic components. I mentioned aluminotherics could explode, and that metallic constituents of the chemical reactants would be far more massive than air molecules. (I didn't explicitly mention thermite, or ferrous constituents.)

I give you full credit for talking to a physics professor. This is good practice.

Yes, solid rockets go "whoosh," not "bang." There's a reason for this. Rockets -- if properly built -- are not explosives. Instead, the rocket situation is referred to as a gas generator. It does not propel the rocket by creating pressure waves, as these tend to reflect inside the rocket motor and destroy it. In solid rockets, including the small Estes type you describe, a common failure mode is for a piece of the solid rocket to become dislodged and choke the nozzle. When this happens, flow rebounds off the obstruction, creating a pressure wave that reflects up the rocket core, and can split the casing. This happened not too long ago on Mythbusters, for instance.

The "whoosh" you hear from a rocket motor is due to reaction gases accelerating. In simple terms, the rocket motor consists of a combustion chamber, with the "burning" propellant at one end generating a volume of gas; and a nozzle, which accelerates the gas. But there is no pressure wave, or at least there had better not be. The gas generation is essentially a static phenomenon which raises the pressure in the combustion chamber. The nozzle allows some of the gas to escape, often supersonically (see Laval nozzle) and produce thrust.

With a gas generator and a nozzle, you can direct gas flow to create a locally strong gust of wind. But this is still awfully inefficient compared to an explosive and its pressure pulse. In the very largest rockets, the force of the backblast is easier to shield against than the heat and even the sound, which exceeds 170 dB SPL in the case of the Space Shuttle. The Shuttle launchpad expends over a quarter million gallons of water during liftoff as sound absorbers, without which the sound would actually destroy the spacecraft!

What does this prove? This proves that the "gust of wind" created by any gas generator, no matter how enormous or efficient, is trivial in terms of destructive force compared to the other possible effects.

He told me to check out magneto waves, Magnetic Hydro-Dynamics, and Alfven (waves?). He said he thought that keeping subsonic should be doable if you control the burn rate. He wasn't too sure about who to best ask regarding the destructiveness, but he seemed to agree that a chemical engineer would be a good person to ask.

He said that the magneto waves in dielectrics are sound waves, but of a sort that travel much slower than regular sound waves. I asked him what sort of dielectrics one could use, and he said "rocket fuel".

Any miscommunication between my professor and myself is probably my fault!

I don't know about "Magneto Waves," but I know about magnetosonic waves (Alfven waves, in the limit of low temperature). These also travel at the local "speed of sound," although since you're in a highly specialized medium, that sound speed can be slower than Mach 1. In general, though, that sound speed is in fact comparable to the speed of light...

Unless you can think of a way to fill the WTC Towers with a low-temperature ionic or electron gas, and permeate it with a strong magnetic field, I don't think this is going to be viable.
 
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metamars, I'd just like to make two brief points.

Debris from higher floors impacted the ground at speeds over 100 mph just from the accelleration imparted by gravity.

Second, how many 10,000-round volleys of .22 long do you think it would take to deliver the energy equivalent to pulverize 220 acres of four-inch-thick concrete? That's a lot of shootin'.
 
Was he talking about thrust setting up standing waves that rip up your guts; like an engine run for a J-58/SR-71 engine; engine in full burner, diamonds patterns, close enough to feel like someone was inside you moving things around.
 
There are no explosives that I know of that would propogate more slowly than an air/fuel bomb. We know three of those were used, jerry-rigged out of air liners.

They did not pulverise the concrete. To pulverize concrete requires a fast-propogating explosive like dynamite, and a great deal of it. You can't do it quitely.

An old hard-rock miner friend of mine once explained to me that for hard rock mining, they use dynamite because it shatters the rock and makes it easy to scoop out.

For quarrying, where they want the stone in the largest pieces they can manage, they use prells or ANFO, ammonium nitrate charges, because they propogate slowly and push the gases relatively gently into the cracks and crevices of the rock and push it apart.

So no, the idea of using a slow-propogating explosive to bust up concrete does not even make sense.
 
Basically, I had suggested a low velocity blast of less than 100 mph, from a tempered thermobaric, as source of the pulverisation. Some people on that thread keep missing the point that I am not positing this as a source of the columns' destruction, but rather pulverization of most of the other stuff. Besides the visuals of the buildings as they were coming down, recall reports of not finding a piece of a phone bigger than the touchpad, or the scarcity of photos that show even a squashed computer screen or shard of glass.

Just when I though the truth movement couldn't come up with a more absurd premise, they prove me wrong. The argument here is as follows:

The conspirators developed a completely unknown and logically contradictory type of explosive. They then placed charges formed from this explosive in the Twin Towers prior to the 9-11 attacks. These novel charges then exploded very, very slowly, pulverising concrete over an enormous area but did not break any windows or expel any debris from the buildings because their maximum gas expansion velocity was within the range of weather-related velocities that the towers were designed to withstand. The purpose of these unheard-of explosives was not to initiate or to accelerate the collapse of the towers, as they could not have had any possible effect on the support columns, but to pulverise telephones, computer screens and glass panels, none of which would in any case have survived the building collapses.

Despite being an atheist, there are times when I find the language of atheism to be inadequate.

In the name of God, why?????

Back in 1987, southern England was hit by a hurricane, with winds gusting well over 100mph. Surprisingly, these winds, which are in the range of speeds Metamars is proposing here, did not cause extensive pulverisation of concrete, despite the exposure to these winds of large area concrete structures in... well, just about everywhere. My house remained standing, despite being made of soft brick - far easier to pulverise than concrete. Plastic toys in my garden were also not pulverised by the 100+mph blast. Just how fragile are your American telephones and computer monitors anyway?

Metamars, if you can take this stuff seriously, you need help.

Dave
 
Back in 1987, southern England was hit by a hurricane, with winds gusting well over 100mph. Surprisingly, these winds, which are in the range of speeds Metamars is proposing here, did not cause extensive pulverisation of concrete, despite the exposure to these winds of large area concrete structures in... well, just about everywhere. My house remained standing, despite being made of soft brick - far easier to pulverise than concrete. Plastic toys in my garden were also not pulverised by the 100+mph blast. Just how fragile are your American telephones and computer monitors anyway?

Metamars, if you can take this stuff seriously, you need help.


I'm glad someone brought this up. I'm having trouble finding a confirmation, but this page says, "The building is a huge sail that must resist a 225 km/h hurricane."

That's about 140mph.

Granted that's a lateral load, but it's also a Category 4 hurricane. metamars' maximum estimate of 100mph is equivalent to a Category 2 hurricane.WP

If you've seen video of a Category 2 hurricane, you'll know that metamars' theory is pure bunk.
 
I think we must have a record for the most inane theories being discussed at one time in multiple threads in the CT forum.
 
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Nano-Aluminum Deflagrations Nearing Detonation

Fast Reaction of Nano-Aluminum: A Study on Fluorination Versus Oxidation


At: http://etd.lib.ttu.edu/theses/available/etd-06012007-132204/unrestricted/Watson_Kyle_Thesis.pdf


Table 8 (truncated): Mach number calculations for the flame speed of the reactions

Al Size Composition Ma in gas medium at reaction temp

50 nm Al/Teflon 1.18
50 nm Al/MoO3/Teflon 0.90
50 nm Al/MoO3 0.87

1-3 micron Al/Teflon 0.49
1-3 micron Al/MoO3/Teflon 0.15
1-3 micron Al/MoO3 0.22


Initially looking at the flame speeds, the reactions appear to approach Mach 3 as shown by the Mach number calculation at room temperature shown in Table 8. If this was the case acoustical effects may play a huge role and detonation in the reaction would be imminent. However, considering the reaction occurs in air at the reaction temperature yields Mach numbers on the subsonic regime and would be more consistent with a deflagration. The actual Mach numbers will most likely be somewhere in between and may be best represented by the Mach number calculation in the gas byproduct medium at the reaction temperature. The number is probably slightly high as the gas will not be at the adiabatic flame temperature but it will be much higher than that of room temperature. These Mach numbers are on the order of Mach 1 and would suggest a reaction that is still a deflagration but may be nearing detonation. This is consistent with the comparison of the optical and acoustical propagation rates from above.

(emphasis mine)
 
That's great, metamars. Too bad you couldn't read the comments above before making a further fool of yourself.

Be sure to keep your nano-aluminum beanie away from magnesium sparks.

Take a photo of Neptune while you're up there. Neptune's cool.
 
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Fast Reaction of Nano-Aluminum: A Study on Fluorination Versus Oxidation

Again from Fast Reaction of Nano-Aluminum: A Study on Fluorination Versus Oxidation


http://etd.lib.ttu.edu/theses/available/etd-06012007-132204/unrestricted/Watson_Kyle_Thesis.pdf

The pressure wave propagation will tell how fast the pressure is moving through the confined space. This can be used to determine if the reaction reaches the point of detonation or if it is a deflagration. If the pressure wave proceeds equal or faster than that of the optical propagation wave the reaction can be considered to have reached detonation. If the pressure wave propagates slower than the optical wave the reaction will be a deflagration.

The optical propagation rate, or flame speed, is deduced from the high-speed camera data. It is primarily used as a quantification for the speed of the reaction, but can also give indication of detonation when compared to the pressure wave propagation rate as described above. Another interesting characteristic derived from the optical propagatioin rate is the Mach number achieved by the reaction. In many MIC reactions, flame speeds can approach and exceed 1000 m/s, which would be in excess of Ma 3 if the surroundings were considered to be air at room temperature. The achieving of such Mach numbers could mean that there are significant acoustic effects in the reaction. However, reaction proceeds within the flame zone assumed to be at the adiabatic flame temperature for the reaction. This extreme temperature environment reduces the Ma number calculation significantly.
.
.
Peak flame speeds of 4.249 m/s, 410.636 m/s, and 456.559 m/s were obtained for the nano Al samples of Al/Teflon, Al/MoO3/Teflon, and Al/MoO3 composites, respectively.

Note: the flame propagation rate varied enormously as a percentage of aluminum. For example, from Figure 11, which plots flame propagation rate vs. % Al for Al/MoO3/Teflon, there are not only supersonic flame rates of about 410 m/s and 360 m/s, there are also flame rates of ~ 230, 80, 10 and 10 m/s.

In other words, we can get both supersonic and subsonic flame rates, the speed of sound in air being 344 m/s.

I'm not sure if this holds for rapid, yet subsonic flame rate regimes, but for the case of 50 nm Al burns of 40% Al, we can see from Table 5 that supersonic, optical propagation rate exceeds the pressure propagation rate for all of the species being studied. Perhaps the same will be true, for example, for a 230 m/s flame propagation rate, but I haven't seen the data for that.
 
So in conclusion it seems the claim is the WTC was pulverised by effectively a big gust of wind? Brilliant. Perhaps we should call it the 'Three Little Pigs Theory'?
 
And in something like, for instance, the wood in your fireplace, the flame rate is in mm/minute.

You can get rates of reaction to be anything you like, up to about Mach 8 for violent fluourine chemistry and down to near zero if you restrict the oxidizer. None of this has any effect on the way pressure waves move in air. No reaction rate will support your hypothesis.
 
I think we must have a record for the most inane theories being discussed at one time in multiple threads in the CT forum.


I am beginning to wonder if Marvel and DC comics are not the Twoofers main source of Scientific Information.
 
Again from Fast Reaction of Nano-Aluminum: A Study on Fluorination Versus Oxidation


http://etd.lib.ttu.edu/theses/available/etd-06012007-132204/unrestricted/Watson_Kyle_Thesis.pdf


.
.


Note: the flame propagation rate varied enormously as a percentage of aluminum. For example, from Figure 11, which plots flame propagation rate vs. % Al for Al/MoO3/Teflon, there are not only supersonic flame rates of about 410 m/s and 360 m/s, there are also flame rates of ~ 230, 80, 10 and 10 m/s.

In other words, we can get both supersonic and subsonic flame rates, the speed of sound in air being 344 m/s.

I'm not sure if this holds for rapid, yet subsonic flame rate regimes, but for the case of 50 nm Al burns of 40% Al, we can see from Table 5 that supersonic, optical propagation rate exceeds the pressure propagation rate for all of the species being studied. Perhaps the same will be true, for example, for a 230 m/s flame propagation rate, but I haven't seen the data for that.

And flame propagation rate is related to shock wave propagation how?

(I see RMackey beat me to it...
He's just too quick...)
 
And in something like, for instance, the wood in your fireplace, the flame rate is in mm/minute.

You can get rates of reaction to be anything you like, up to about Mach 8 for violent fluourine chemistry and down to near zero if you restrict the oxidizer. None of this has any effect on the way pressure waves move in air. No reaction rate will support your hypothesis.

Table 16 shows avg. results for Al/Fl 1-3 microns, with peak pressure of 606 psi and propagation rate of 186 m/s. Do you think this will create an explosive shock wave, or not? And what do you think will happen to office materials exposed to a 606 psi pressure, at God knows what temperature? I haven't finished studying the report (not sure I will), so I don't even know if the author discusses the drop-off behavior of the peak pressure with distance.

Unfortunately, the author seems to have only presented the most energetic, supersonic cases for 50 nm Al. I am most interested in the subsonic, 50 nm Al case....
 
Table 16 shows avg. results for Al/Fl 1-3 microns, with peak pressure of 606 psi and propagation rate of 186 m/s. Do you think this will create an explosive shock wave, or not? And what do you think will happen to office materials exposed to a 606 psi pressure, at God knows what temperature?
Hell, you could blow the whole building apart with 15 psi at ambient air temperature. Try to think about what you're missing here, metamars.
 
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Table 16 shows avg. results for Al/Fl 1-3 microns, with peak pressure of 606 psi and propagation rate of 186 m/s. Do you think this will create an explosive shock wave, or not? And what do you think will happen to office materials exposed to a 606 psi pressure, at God knows what temperature? I haven't finished studying the report (not sure I will), so I don't even know if the author discusses the drop-off behavior of the peak pressure with distance.

Unfortunately, the author seems to have only presented the most energetic, supersonic cases for 50 nm Al. I am most interested in the subsonic, 50 nm Al case....

Sigh.

If you create a pressure wave of 606 PSI, this wave propagates at the speed of sound. Or more, depending on its continuity.

The burning rate ("propagation" as you have it here) is something totally different. This determines how long this pressure is sustained, by describing how long it takes to exhaust your reactants. It has nothing to do with how fast the pressure wave travels.

Temperature is a totally different phenomenon. You started this on a quest for "pulverization" at low speed, remember?
 
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Anyone who has been to Taco Bell knows very well there are mere 100mph explosives.
 
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And flame propagation rate is related to shock wave propagation how?

(I see RMackey beat me to it...
He's just too quick...)


'everything subsonic scenario'
---------------------------------
if
pressure propagation rate < flame rate
and if
flame rate < speed of sound

then

pressure propagation rate < speed of sound

In other words, all relevant speeds are subsonic.



From the paper, we can see that there are cases where
pressure propagation rate < flame rate
and
flame rate > speed of sound


Unfortunately, from what I've seen to far of the paper, he doesn't present data for us to know if the 'everything subsonic scenario' exists for the species the studies, or not. Do you agree with this statement?
 
'everything subsonic scenario'
---------------------------------
if
pressure propagation rate < flame rate
and if
flame rate < speed of sound

This is false!

Pressure propagation rate => speed of sound.

Always.

Period.

It's the bloody definition of pressure. If you're a condensed matter physics guy, pressure is transmitted at the phonon speed, unless mechanical motion exceeds it. If you're a fluid dynamicist, you can solve for pressure as a function of location and time using Navier-Stokes. This is true for any and all phenomena that affect pressure.

That's all there is to it. Don't think about anything else until you grasp this fact.
 
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Sigh.

If you create a pressure wave of 606 PSI, this wave propagates at the speed of sound. Or more, depending on its continuity.

The burning rate ("propagation" as you have it here) is something totally different. This determines how long this pressure is sustained, by describing how long it takes to exhaust your reactants. It has nothing to do with how fast the pressure wave travels.

Temperature is a totally different phenomenon. You started this on a quest for "pulverization" at low speed, remember?

There some kind of disconnect between what the author says (or what I think he's saying), and what you are saying (or what I think you are saying.)

If you look on page 73, table 16, in the AVG row you will see the figures I have quoted. My interpretation of 606 psi is that this is the total peak pressure from all sources, which includes gaseous pressure waves as well as solid, incompletely combusted particles, which will also impart kinetic energy. Since, as you pointed out, the overpressure due to a 100 mph wind is only .17 psi, I expect almost all of the 606 psi pressure to be due to the kinetic energy of the aluminothermic powder, and not due to gas pressure.

Actually, the 186 m/s propagation rate is a (also) a bit nebulous, as it's not clear whether he is talking about 1) just the pressure wave, 2) the flame propagation, or 3) whichever comes first. (I suppose, in the unlikely event that they impact the sensor at the same velocity, it could also mean 4) the combined pressure/flame front.)

In short, I don't think the author is claiming a "pressure wave of 606 psi".
 
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There some kind of disconnect between what the author says (or what I think he's saying), and what you are saying (or what I think you are saying.)
Focus on the highlighted parts.

Actually, the 186 m/s propagation rate is a (also) a bit nebulous, as it's not clear whether he is talking about 1) just the pressure wave,
NO!
 
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